Karakterisasi Karbon Aktif Asal Tumbuhan dan Tulang Hewan Menggunakan FTIR dan Analisis Kemometrika
Abstract
Activated carbon is widely used as an adsorbent in gas purification, refining pulp, and also for the purification of food products, among others, oil purification, refining cane sugar, beet sugar, corn sugar, eliminate the taste and odor of drinking water. Carbon active can be derived from plant and animal bone. This study aims to analyze the differences in spectral profile of activated carbon from plants and animal bones by using FTIR. The data combined with the results of FTIR analysis chemometrics to classify and categorize the data, so it is clear where the activated carbon from plants and animal bones. FTIR analysis methods combined with chemometrics analysis through modeling PCA (Principal Component Analysis) and PLS-DA (Partial Least Squares-Discriminant Analysis) is able to distinguish between activated carbon derived from plants (coconut shell) and animal bones (beef and pork). PCA with total diversity of 89% were able to classify the samples of activated carbon plant and animal bones. PLSDA models successfully predicted the test sample is based on a sample group of activated carbon raw material. Manufacture of activated carbon predictive models with PLS calibration generates R2, R2 predictions, RMSEC, and RMSEP respectively by 0.9787389, 0.9662152, 0.0687364 and 0.0928362. The results showed that FTIR spectra and can be used to distinguish chemometrics activated carbon derived from plant and animal bones
Keywords
References
Alfiany H, Bahri S, Nurakhirawati. 2013. Kajian penggunaan arang aktif tongkol jagung sebagai adsorben logam Pb dengan beberapa aktivator asam. Jurnal Natural Science. 2(3): 75-86. ISSN: 2338-0950.
Badan Standarisasi Nasional. 2011. SNI 06-3730-1995: Arang Aktif Teknis. Jakarta (ID): Badan Standardisasi Nasional.
Bani M, Santjojo DH, Masruroh. 2013. Pengaruh suhu reaksi reduksi terhadap pemurnian karbon berbahan dasar tempurung kelapa. Jurnal Natural B. 2(2).
Baranska W. 2005. Quality control of harpagophytum procumbensand its related phytopharmaceutical products by means of NIR-FT-Raman spectroscopy. Biopolymers. 77:1-8.
Bledzki AK, Mamun AA, Volk J. 2010. Barley husk and coconut shell reinforced polypropylene composites: The effect of fibre physical, chemical and surface properties. Composites Science and Technology. 70: 840-846.
Chand, Bansal, Roop, Meenakshi Goyal. 2005. Activated Carbon Adsorpsion. United States of America (USA): Lewis Publisher.
Chew OS, Hamdan MR, Ismail Z, Ahmad MN. 2004. Assessment of herbal medicine by chemometrics: Assisted Interpretation of FTIR Spectra. J Anal Chem Acta, in press
Dahlan K, Sari YW, Yuniarti E, Soejoko DS. 2006. Karakterisasi gugus fosfatdan karbonat dalam tulang tikus dengan fourier transform infrared (FT-IR) spectroscopy. Jurnal sains materi Indonesia.
Fessenden dan Fessenden.1986. Kimia Organik Jilid 1.Ed Ke-3. Pudjaatmaka AH, penerjemah. Jakarta (ID): Erlangga.
Gad HA, Ahmady SH, Abou Shoer MI, Al-Azizi MM. 2012. Application of chemometrics in authentication of herbal medicines: A Review. Phytochemical Analysis. 24:1-24.
Hashim DM, Che Man YB, Norakasha R, Shuhaimi M, Salah Y, Syahariza ZA. 2010. Potential use of fourier transform infra red spectroscopy for differentiation of bovine and porcine gelatins. Food chemistry. 118: 856-860.
Hendra, Darmawan, 2000. Pengaruh bahan baku, jenis perekat dan tekanan kempa terhadap kualitas briket arang. Bogor (ID): Puslitbang Hasil Hutan Bogor.
Hendra D, Winarni I. 2003. Sifat fisis dan kimia briket arang campuran limbah kayu gergajian dan sebetan kayu. Jurnal Penelitian Hasil Hutan. 2(31): 211-226.
Jankowska H, Swiatkowski A, Choma J. 1991. Active Carbon 1st Ed. New York (USA): Ellis Horwood.
Juliandini F, TrihadiningrumY. 2008. Uji kemampuan karbon aktif dari limbah kayu dalam sampah kota untuk penyisihan fenol. Surabaya (ID): Seminar Nasional Manajemen Teknologi VII. ISBN: 9798-979-99735-4-2.
Kumosinski TF, Farrell JrHM. 1993. Determination of the global secondary structure of proteins by fourier transforrn infrared (FTIR) spectroscopy. Trends in Food Sci. dan Technol. 6(4): 169- 175.
Kurniawan R, Lutfi M, Agung WN. 2014. Karakterisasi luas permukaan bet (braunanear, emmelt dan teller) karbon aktif dari tempurung kelapa dan tandan kosong kelapa sawit dengan aktivasi asam fosfat (H3PO4). Jurnal Keteknikan Pertanian Tropis dan Biosistem. 2(1): 15-20.
Lokapuspita G, Hayati M, Purwanto. 2012. Pemanfaatan limbah ikan nila sebagai fishbone hydroxyapatite pada proses adsorpsi logam berat krom pada limbah cair. Jurnal Teknologi Kimia Dan Industri. 1(1): 379-388.
Maftuhin TA, Hanifah, Anita S. 2014. Potensi pemanfaatan tulang ayam sebagai adsorben kation timbal dalam larutan. Jurnal Fakultas MIPA. Universitas Riau.
Manocha SM. 2003. Porous carbons. Journal Sadhana. 28:1-2.
Marlina Elin. 2013. Aplikasi kemometrik untuk kendali mutu simplisia kumis kucing (Orthosiphon aristalus). [skripsi]. Bogor (ID): Departemen Kimia. Institut Pertanian Bogor.
Naes T, Isaksson T, Fearn T, Davies T. 2002. A user friendly guide to multivariate calibration and classification. Chichester (UK): NIR Publication
Novicio LP, Hata, Kajimoto T, Imamura Y, Ishihara S. 1998. Removal of mercury from aqueous solutions of mercuric chloride using wood powder carbonized at high temperature. Journal of Wood Research. 85: 48-55.
Pambayun GS, Yulianto, Remigius YE, Rachimoellah M, Putri, Endah MM. 2013. Pembuatan karbon aktif dari arang tempurung kelapa dengan aktivator ZnCl2 dan Na2CO3 sebagai adsorben untuk mengurangi kadar fenol dalam air limbah. Jurnal Teknik POMITS. 2(1): ISSN: 2337-3539.
Pari G. 1996. Kualitas arang aktif dari 5 jenis kayu. Buletin Penelitian Hasil Hutan. 14: 60-68.
Pari G. 2004. Kajian struktur arang aktif dari serbuk gergaji kayu sebagai adsorben formaldehida kayu lapis. [disertasi]. Bogor (ID): Program Pascasarjana, Institut Pertanian Bogor.
Pujiarti P, Sutapa JPG. 2005. Mutu arang aktif dari limbah kayu mahoni (Swietenia macrophyllaking) sebagai bahan penjernih air. J.Ilmu dan Teknologi Kayu Tropis. 3(2).
Purwakusumah ED, Rafi M, Syafitri UD, Nurcholis W, Adzkiya MAZ. 2014. Identifikasi dan autentikasi jahe merah menggunakan kombinasi spektroskopi FTIR dan kemometrik. Agritech. 34(1).
Ramdja AF, Halim M, Handi Jo. 2008. Pembuatan karbon aktif dari pelepah kelapa (Cocus nucifera). Jurnal Teknik Kimia. 15(2).
Rezaee A, Rangkooy H, Jonidi A, Jafari A, Khavanin A. 2013. Surface modification of bone char for removal of formaldehyde from air. Journal Applied Surface Science. 286: 235–239.
Rohman A, Sismindari, Erwanto Y, and Che Man YB. 2011. Analysis of pork adulteration in beef meatball using fourier transform infrared (FTIR) spectroscopy. Meat Science. 88: 91–95.
Rohaeti E, Heryant R, Rafi M, Wahyuningrum A, dan Darusman LK. 2011. Prediksi kadar flavonoid total tempuyung (Sonchus arvensis L.) menggunakan kombinasi spektroskopi IR dengan regresi kuadrat terkecil parsial. Jurnal Kimia. 5(2).
Stchur P, Cleveland D, Zhou J, Michel RG. 2002. A review of recent aplications of near infrared spectroscopy and of the caracteristics of novel Pbs CCD array based NIR spectrometers. App Spect Rev. 37:383-428
Suhendarwati L, Suharto B, Susanawati LD. 2013. Pengaruh konsentrasi larutan kalium hidroksida padaabu dasar ampas tebu teraktivasi. Jurnal Sumberdaya Alam dan Lingkungan.
Syamberah, Anita S, Hanifa TA. 2015. Potensi arang aktif dari tulang sapi sebagai adsorben ion besi, tembaga, sulfat dan sianida dalam larutan. JOM FMIPA. 2(1).
Varmuza K. 2002. Applied chemometrics: from chemical data to relevant information. Cairo (EGP): 1st Converence on Chemistry.
Wijayanti R. 2009. Arang aktif dari ampas tebu sebagai adsorben pada pemurnian minyak goreng bekas. [tesis]. Bogor (ID): Program Pasca Sarjana, Bidang Ilmu Kimia, Institut Pertanian Bogor.
Wold S, Sjostrom M, Eriksson L. 2001. PLSregression: a basic tool of chemometrics. Chem Intel Lab Syst. 58:109-130.
Yusuf MA, Tjahjani S. 2013. Adsorpsi ion Cr (VI) oleh arang aktif sekam padi. UNESA Journal of Chemistry. 2(1).
Zhao F, Yin Y, Lu WW, Leong JC, Zhang W, Zhang J, Zhang M, Yao K. 2002. Preparation and histological evaluation of biomimetic three dimensional HA/chitosan-gelatin network composite scaffolds.
Biomaterials. 23: 3227-3234.
Zou HB, Yang GS, Qin ZR. 2005. Progress in quality control of herbal medicine with IR fingerprint spectra. Analytical Letters. 38: 1457-1475.
DOI: 10.15408/jkv.v0i0.3146
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