Zeolite from Zirconium-Modified Fly Ash Waste for Absorption of Phosphate Compounds in Waters
Abstract
Eutrophication is a phenomenon of decreasing air quality caused by the very high amount of phosphate ions in the aquatic system. Thus, an effective and efficient adsorbent is needed for phosphate absorption in aquatic systems. In this study, zeolit from fly ash waste was modified with zirconium (Zr) as an adsorbent for phosphate absorption in aquatic systems. Fly ash was pretreated with acid and then synthesised using the hydrothermal method. And then, the results of the fly ash zeolit synthesis were continued using zirconium. The adsorption capacity was tested through several parameters, including the adsorbent concentration test, variations in pH,and contact time. Zirconium-modified zeolite (ZrMZ) adsorbent was the most effective adsorbent for phosphate adsorption, with an adsorption capacity of 3.015 mg-P/g at a 3 g/L adsorbent dosage and pH 7. The adsorption kinetics for the ZrMZ adsorbent followed pseudo-second-order kinetics. The best result of ZrMZ adsorbent to absorb phosphate in lake water was an adsorption capacity value of 0.186 mg-P/g and an adsorption efficiency of 81.137%.
Keywords
References
Ahdiaty, R., & Fitriana, D. (2020). Pengambilan Sampel Air Sungai Gajah Wong di Wilayah Kota Yogyakarta. IJCA (Indonesian Journal of Chemical Analysis), 3(2), 65–73. https://doi.org/10.20885/ijca.vol3.iss2.art4
Aryee, A. A., Dovi, E., Shi, X., Han, R., Li, Z., & Qu, L. (2021). Zirconium and iminodiacetic acid modified magnetic peanut husk as a novel adsorbent for the sequestration of phosphates from solution: Characterization, equilibrium and kinetic study. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 615. https://doi.org/10.1016/j.colsurfa.2021.126260.
Byrappa, K. (2007). Characterization of zeolites by infrared spectroscopy Triazole derivatives View project Microwave Assisted Synthesis and Characterization of Nanostructure Zinc Oxide-Graphene Oxide and Photo Degradation of Brilliant Blue View project. In Article in Asian Journal of Chemistry. https://www.researchgate.net/publication/283862901.
Chitrakar, R., Tezuka, S., Sonoda, A., Sakane, K., Ooi, K., & Hirotsu, T. (2006). Selective adsorption of phosphate from seawater and wastewater by amorphous zirconium hydroxide. Journal of Colloid and Interface Science, 297(2), 426–433. https://doi.org/10.1016/j.jcis.2005.11.011.
Deng, L., Xu, Q., & Wu, H. (2016). Synthesis of Zeolite-like Material by Hydrothermal and Fusion Methods Using Municipal Solid Waste Fly Ash. Procedia Environmental Sciences, 31, 662–667. https://doi.org/10.1016/j.proenv.2016.02.122.
Dwi Jananti, P., Kusumastuti Jurusan Kimia, E., & Matematika dan Ilmu Pengetahuan Alam, F. (n.d.). Sintesis Zeolit A Dari Abu Layang Batubara Melalui Modifikasi Proses Hidrotermal.
Faradilla, A. R., Yulinawati, H., Suswantoro, E., Lingkungan, J. T., Lansekap, A., & Lingkungan, T. (2016). Pemanfaatan Fly Ash Sebagai Adsorben Karbon Monoksida Dan Karbon Dioksida Pada Emisi Kendaraan Bermotor. Seminar Nasional Cendekiawan.
Goscianska, J., Ptaszkowska-Koniarz, M., Frankowski, M., Franus, M., Panek, R., & Franus, W. (2018). Removal of phosphate from water by lanthanum-modified zeolites obtained from fly ash. Journal of Colloid and Interface Science, 513, 72–81. https://doi.org/10.1016/j.jcis.2017.11.003.
Herpi, A., Yunarti, R., & Saefumillah, A. (2021, October 19). Synthesized Zeolite from Coal Fly Ash: Effect of Furnace and Acidic Pretreatment on the Characteristic. https://doi.org/10.4108/eai.19-12-2020.2309115.
Isiuku, B. O., Enyoh, C. E., Duru, C. E., & Ibe, F. C. (2021). Phosphate ions removal from aqueous phase by batch adsorption on activated (activation before carbonization) biochar derived from rubber pod husk. Current Research in Green and Sustainable Chemistry, 4. https://doi.org/10.1016/j.crgsc.2021.100136.
Jumaeri, Jananti, P. D., & Kusumastuti, E. (2013). Sintesis Zeolit A Dari Abu Layang Batubara Melalui Modifikasi Proses Hidrotermal.
Lalley, J., Han, C., Li, X., Dionysiou, D. D., & Nadagouda, M. N. (2016). Phosphate adsorption using modified iron oxide-based sorbents in lake water: Kinetics, equilibrium, and column tests. Chemical Engineering Journal, 284, 1386–1396. https://doi.org/10.1016/j.cej.2015.08.114.
Li, M., Liu, J., Xu, Y., & Qian, G. (2016). Phosphate adsorption on metal oxides and metal hydroxides: A comparative review. In Environmental Reviews (Vol. 24, Issue 3, pp. 319–332). Canadian Science Publishing. https://doi.org/10.1139/er-2015-0080.
Ma, H., Zhang, J., Wang, M., & Sun, S. (2019). Modification of Y-Zeolite with Zirconium for Enhancing the Active Component Loading: Preparation and Sulfate Adsorption Performance of ZrO(OH)2/Y-Zeolite. ChemistrySelect, 4(27), 7981–7990. https://doi.org/10.1002/slct.201901519.
Patty, S. I. (2014). Characteristics of Phosphate, Nitrate and Dissolved Oxygen in Gangga and Siladen Island Waters, North Sulawesi. Jurnal Ilmiah Platax, 2(2). http://ejournal.unsrat.ac.id/index.php/platax.
Poernomo, H., Biyantoro, D., & MariaVeronica Purwani Pusat Teknologi Akselerator dan Proses Bahan -BATAN Jalan Babarsari Kotak Pos, dan. (n.d.). Kajian Konsep Teknologi Pengolahan Pasir Zirkon Lokal Yang Mengandung Monasit, Senotim, Dan Ilmenit, The Concept Study Of Processing Technology Of Local Zircon Sand Containing Monazite, Xenotime, And Ilmenite.
Ragheb, S. M. (2013). Phosphate removal from aqueous solution using slag and fly ash. HBRC Journal, 9(3), 270–275. https://doi.org/10.1016/j.hbrcj.2013.08.005.
Rayalu, S., Meshram, S. U., & Hasan, M. Z. (2000). Highly crystalline faujasitic zeolites from flyash. In Journal of Hazardous Materials (Vol. 77). www.elsevier.nlrlocaterjhazmat.
Rodrigues, L. A., Maschio, L. J., Coppio, L. D. S. C., Thim, G. P., & da Silva, M. L. C. P. (2012). Adsorption of phosphate from aqueous solution by hydrous zirconium oxide. Environmental Technology (United Kingdom), 33(12), 1345–1351. https://doi.org/10.1080/09593330.2011.632651.
Safitri, L. E., Zuryati, U. K., Rohma, H. N., Ni’Mah, Y. L., & Prasetyoko, D. (2020). Synthesis zeolite y from kaolin bangka belitung: Activation of metakaolin with various concentration of sulfuric acid. Journal of Physics: Conference Series, 1567(3). https://doi.org/10.1088/1742-6596/1567/3/032099.
Salehi, S., Alijani, S., & Anbia, M. (2020). Enhanced adsorption properties of zirconium modified chitosan-zeolite nanocomposites for vanadium ion removal. International Journal of Biological Macromolecules, 164, 105–120. https://doi.org/10.1016/j.ijbiomac.2020.07.055.
Sasongko, E. B., Widyastuti, E., & Priyono, R. E. (2014). Kajian Kualitas Air Dan Penggunaan Sumur Gali Oleh Masyarakat Di Sekitar Sungai Kaliyasa Kabupaten Cilacap. 12, 72–82.
Simbolon, A. R. (n.d.). Pencemaran Bahan Organik dan Eutrofikasi di Perairan Cituis, Pesisir Tangerang.
Xiong, W., Tong, J., Yang, Z., Zeng, G., Zhou, Y., Wang, D., Song, P., Xu, R., Zhang, C., & Cheng, M. (2017). Adsorption of phosphate from aqueous solution using iron-zirconium modified activated carbon nanofiber: Performance and mechanism. Journal of Colloid and Interface Science, 493, 17–23. https://doi.org/10.1016/j.jcis.2017.01.024.
Yang, M., Lin, J., Zhan, Y., & Zhang, H. (2014). Adsorption of phosphate from water on lake sediments amended with zirconium-modified zeolites in batch mode. Ecological Engineering, 71, 223–233. https://doi.org/10.1016/j.ecoleng.2014.07.035.
Yang, M., Lin, J., Zhan, Y., Zhu, Z., & Zhang, H. (2015). Immobilization of phosphorus from water and sediment using zirconium-modified zeolites. Environmental Science and Pollution Research, 22(5), 3606–3619. https://doi.org/10.1007/s11356-014-3604-2.
Zahrah, N., Saefumillah, A., & Yunarti, R. T. (2020). Study of phosphate adsorption from aquatic system using fly ash residue modified with magnetite (Fe3O4). AIP Conference Proceedings, 2242. https://doi.org/10.1063/5.0010656.
Zhang, K., van Dyk, L., He, D., Deng, J., Liu, S., & Zhao, H. (2021). Synthesis of zeolite from fly ash and its adsorption of phosphorus in wastewater. Green Processing and Synthesis, 10(1), 349–360. https://doi.org/10.1515/gps-2021-0032.
Zhang, P., He, M., Huo, S., Li, F., & Li, K. (2022). Recent progress in metal-based composites toward adsorptive removal of phosphate: Mechanisms, behaviors, and prospects. Chemical Engineering Journal, 446, 137081. https://doi.org/10.1016/j.cej.2022.137081.
DOI: 10.15408/jkv.v9i1.26951
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