Effect of HCl/γ-Al2O3 and HCl/Ni/γ-Al2O3 Catalyst on The Cracking of Palm Oil

Alda Titania Dewanti, Rismawati Rasyid, Ruslan Kalla

Abstract


Fuel oil has a deficit every year. Therefore, a substitute fuel is needed, which can be obtained more efficiently. One of the alternative fuels that have been widely researched is biofuel. Catalytic cracking is a method of producing biofuels such as biogasoline (C5-C9), bioavtur (C10-C15) and green diesel (C16-C22). This research aims to produce biofuels by catalytic cracking of palm oil using HCl/γ-Al2O3 and HCl/Ni/γ-Al2O3 catalysts (1, 3, 5 and 7%). The catalyst was prepared by wet impregnation and characterized by x-ray diffraction, Brunauer Emmett teller and ASTM-D664. The reaction cracking process was operated at a constant temperature of 370 °C, 50 ml volume, and 1 atm pressure. The best catalyst for cracking palm oil is HCl/Ni/γ-Al2O3 (5%) with a yield of 81%, selectivity to biogasoline at 6.41%, bioavtur at 33.81%, and green diesel at 20.33%.


Keywords


Bioavtur; biogasoline; catalytic cracking; green diese

References


Adhani, L., Masrida, R., Angela, N. P., & Nugroho, R. R. (2020). Analisis Efektivitas Katalis Fe/Zeolit pada Cracking Minyak Jelantah dalam Pembuatan Biofuel. PENDIPA Journal of Science Education, 4(1), 7–11. https://doi.org/10.33369/pendipa.4.1.7-11

Aini, A. N., Al-Muttaqii, M., Roesyadi, A., & Kurniawansyah, F. (2020). Kinerja Katalis Ni-Cu/HZSM-5 dalam Pembuatan Biogasoil dari Minyak Bintaro (Cerbera Manghas) dengan Proses Hydrocracking. Jurnal Berkala Saintek, VIII(3), 84–88.

Alimin, A. A., & Susanto, B. H. (2018). Simulation of a Bioavtur Production Process from Non-Edible Vegetable Oil. E3S Web of Conferences, 67(02022), 1–7. https://doi.org/10.1051/e3sconf/20186702022

Aziz, I., Kurnianti, Y., Saridewi, N., Adhani, L., & Permata, W. (2020). Utilization of Coconut Shell as Cr2O3 Catalyst Support for Catalytic Cracking of Jatropha Oil into Biofuel. Jurnal Kimia Sains Dan Aplikasi, 23(2), 39–45. https://doi.org/10.14710/jksa.23.2.39-45

Badriyah, L., & Falah, I. I. (2017). Gasoline Production from Coconut Oil Using The Ni-MCM-41 and Co/Ni-MCM-41 Catalyst. JKPK (Jurnal Kimia Dan Pendidikan Kimia), 2(1), 22. https://doi.org/10.20961/jkpk.v2i1.8516

Budianto, A., Sari, A. R., Monica, Y. W., Ningsih, E., & Kusdarini, E. (2019). Proses Pembuatan Biofuel dengan Metode Perengakahan menggunakan Katalis Padat. Journal of Industrial Process and Chemical Engineering, 1(2), 25–31.

Budianto, A., Sumari, S., Pambudi, W. S., Andriani, N., & Mardianto, A. A. (2019). Uji Coba Produksi Biofuel dari RBD Stearin dalam Reaktor Fixed Bed dengan Metode Cracking. In Prosiding Seminar Nasional Sains dan Teknologi Terapan (pp. 735–740).

Carli, M. F., Susanto, B. H., & Habibie, T. K. (2018). Sythesis of Bioavture Through Hydrodeoxygenation and Catalytic Cracking from Oleic Acid using NiMo/Zeolit Catalyst. E3S Web of Conferences, 67(02023), 1–5. https://doi.org/10.1051/e3sconf/20186702023

Delmon, B., Haber, J., & Block, J. H. (1995). Manual of Methods and Procedures for Catalyst Characterization. International Union Pure and Applied Chemistry (Vol. 67). https://doi.org/10.1351/pac199567081257

Dewanti, A. T., Fitrah, M., Setiawan, B., Suryanto, A., & Rasyid, R. (2021). Uji Aktifitas Katalis NaOH/Ni/gamma Al2O3 pada Proses Transesterifikasi Minyak Sawit. Journal of Chemical Process Engineering Volume, 6(1), 53–58.

Hajj, D. S., Aprilia, D., & Budianto, A. (2019). Pembuatan Biofuel dengan Proses Perengkahan dari Palm Fatty Acid Distillate ( PFAD ) menggunakan Katalis CaO. In Seminar Nasional Sains dan Teknologi Terapan VII 2019 Institut Teknologi Adhi Tama Surabaya (pp. 607–614).

Khodijah, S., & Irsan, F. (2020). Potensi Pengembangan Biodiesel Kelapa Sawit dengan Katalis Limbah Udang di Sumatera Selatan. In Seminar Nasional Lahan Suboptimal (pp. 978–979). Retrieved from http://conference.unsri.ac.id/index.php/lahansuboptimal/article/view/1997

Latipah, N., Sundaryono, A., & Elvia, R. (2017). Produksi Biofuel dari Limbah CPO dengan Katalis Berbasis Titanium Oksida dan Implementasinya pada Pembelajaran Kimia (Biofuel Production of CPO Waste with Ni/Tio 2 and Co/Tio 2 Catalyst and Implementation Of Chemical Learning ). FKIP Universitas Bengkulu, 2(1), 19–24.

Lestari, S., Sundaryono, A., & Elvia, R. (2019). Preparasi dan Karakterisasi Katalis Mo-Ni/HZ dengan Metode Impregnasi untuk Cracking Katalitik Minyak Limbah Cair Pengolahan Kelapa Sawit menjadi Bahan Bakar Nabati. ALOTROP, Jurnal Pendidikan Dan Ilmu Kimia, 3(1), 91–97. https://doi.org/10.33369/atp.v3i1.9047

Monde, J., Kumalasari, P. I., & Nugroho, K. (2019). Perengkahan Metil Ester dari Minyak Jelantah Menggunakan Katalis Pt/Al2O3. CHEESA: Chemical Engineering Research Articles, 2(2), 75–82.

Muryati, T. S., Sundaryono, A., & Handayani, D. (2018). Pembuatan Biofuel dari Limbah Cair PMKS dengan Katalis MoCo-HZ. ALOTROP, Jurnal Pendidikan Dan Ilmu Kimia, 2(2), 161–165.

Rasyid, R., Sabara, Z., Ainun Pratiwi, H., Juradin, R., & Malik, R. (2018). The Production of Biodiesel from A Traditional Coconut Oil Using NaOH/γ-Al2O3 Heterogeneous Catalyst. IOP Conference Series: Earth and Environmental Science, 175(1), 2–8. https://doi.org/10.1088/1755-1315/175/1/012025

Savitri, Nugraha, A. S., & Aziz, I. (2016). Pembuatan Katalis Asam (Ni/γ-Al2O3) dan Katalis Basa (Mg/γ-Al2O3) untuk Aplikasi Pembuatan Biodiesel dari Bahan Baku Minyak Jelantah. Jurnal Kimia VALENSI: Jurnal Penelitian Dan Pengembangan Ilmu Kimia, 2(1), 1–10.

Tambun, R., Burmana, A. D., & Alexander, V. (2021). Pengaruh Konsentrasi Katalis Asam Sulfat dan Waktu Reaksi pada Pembuatan Biodiesel dari Asam Lemak Kelapa Sawit. Jurnal Teknologi Industri Pertanian, 15(1), 345–353.

Tambun, R., Saptawaldi, R. P., Nasution, M. A., & Gusti, O. N. (2016). Pembuatan Biofuel dari Palm Stearin dengan Proses Perengkahan Katalitik menggunakan Katalis ZSM-5. Jurnal Rekayasa Kimia Dan Lingkungan, 11(1), 46–52. https://doi.org/10.1302/0301-620x.59b3.893510

Zurohaina, Z., Zikri, A., Febriana, I., Amin, J. M., Pratiwi, A., Pratiwi, M., & Reyhan, M. H. (2020). Pengaruh Jumlah Katalis Dan Temperatur Pada Proses Pembuatan Bahan Bakar Cair Limbah Styrofoam Dengan Metode Catalytic Cracking. Jurnal Kinetika, 11(01), 9–17. Retrieved from https://jurnal.polsri.ac.id/index.php/kimia/index


Full Text: PDF

DOI: 10.15408/jkv.v8i2.25774

Refbacks

  • There are currently no refbacks.


Copyright (c) 2022 Alda Titania Dewanti, Rismawati Rasyid, Ruslan Kalla

Creative Commons License
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.