Analisis Fasa, Struktur Kristal dan Sifat Kemagnetan Material Komposit Berbasis Nd0,6Sr0,4MnO3 / Fe2O3

Mujadid Al-Rabi, Arif Tjahjono, sitti Ahmiatri Saptari

Abstract


Pada penelitian ini dipelajari rekayasa struktur material komposit berbasis neodymium manganit, yang dimulai dengan mensintesis material Nd0,6Sr0,4MnO3 (NSMO) dengan menggunakan metode sol-gel, lalu dilanjutkan dengan sintesis material komposit (Nd0,6Sr0,4MnO3)1-x/(Fe2O3)x (x= 0; 0,3; 0,5 dan 0,7). Sampel dikarakterisasi dengan menggunakan XRD (X-Ray Diffraction) menunjukkan bahwa sampel NSMO memiliki struktur kristal orthorombik dengan space group P n m a, pengkompositan dengan Fe2O3 tidak menyebabkan perubahan struktur tetapi muncul fasa lain yang ditandai dengan adanya puncak difraksi milik Fe2O3. Karakterisasi FESEM (Field Emission Scanning Electron Microscope) menunjukkan persebaran butir yang merata dengan ukuran butir rata-rata 0.186 μm. Karakterisasi VSM (Vibrating Sample Magnetometer) pada temperatur ruang (298 K) dengan medan magnet 5 T, menunjukkan material komposit NSMO / Fe2O3 bersifat paramagnetik dan nilai magnetisasi serta susceptibilitas sampel semakin menurun seiring dengan penambahan konsentrasi Fe2O3.


Keywords


Anoda Li4Ti5O12, baterai ion lithium, metode solid state

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References


I. A. Abdel-Latif, “Rare Earth Manganites and their Applications,” J. Phys., vol. 1, no. 3, pp. 15–31, 2012.

B. Viswanathan, V. Suryakumar, B. Venugopal, S. H. Roshna, and N. Hariprasad, “Perovskite Materials an Introduction,” 2019.

V. R. Sakhalkar, “Structural, Magnetic and Surface Properties Of RF Magnetron Sputtered Undoped Lanthanum Manganite Thin Films,” The University Of Texas At Arlington, 2009.

S. O. Manjunatha, A. Rao, T. Lin, C. Chang, and Y. Kuo, “Effect of Ba substitution on structural , electrical and thermal properties of La0.65Ca0.35-xBaxMnO3 (O<< x <<0.25) manganites,” J. Alloys Compd., vol. 619, pp. 303–310, 2015.

R. K. Nekouei and V. Sahajwalla, “A Green Route to Synthesize Pr3+/Dy3+ -Doped Nd2O3 Nanoreplicas from Nd−Fe−B Magnets,” ACS Sustain. Chem. Eng., 2017.

M. Korotin, “Spin and orbital ordering of Nd1-xSrxMnO3 from LSDA+U calculations,” Phys. Rev. B, vol. 59, no. 15, pp. 9903–9910, 1999.

M. Noumi, F. Issaoui, E. Dhahri, and E. K. Hlil, “Study of Critical Behavior and Magnetocaloric Effect in Nd1−xSrxMnO3 Compounds,” Jounal Supercond. Nov. Magn., pp. 1507–1516, 2019.

A. M. Ahmed, H. F. Mohamed, A. K. Diab, and S. A. Mohamed, “Synthesis, characterization and low field magnetotransport of Nd0.6Sr0.4MnO3/CrO3 composite,” Indian J Phys, 2016.

B. Balaraju et al., “Structural, Optical and Magnetic Properties of α-Fe2O3 Nanoparticles,” Jounal Mech. Mater. Eng., pp. 0–5, 2017.

M. A. Islam, “Direc Comparison of the Magnetic Properties of Gd0.7Sr0.3MnO3 Nanoparticles with Bulk Counterparts,” University of Engineering & Technology Dhaka 1000, 2012.

N. Perdrial, “Quantitative X-Ray Diffraction : X’Pert Highscore Plus Rietveld Module,” 2010.

J. Setiawan, “Introduction Rietveld Analysis in X’Pert Highscore Plus,” no. May, 2018.

G. Venugopal Reddy, P.;Prasad, V.;Venkataiah, “Anomalous variation of magnetoresistance in Nd0.67-y Euy Sr0.33 Mn O3 manganites,” Solid State Commun., vol. 141, no. 0, pp. 73–78, 2007.

E. Handoko, B. Soegijono, and F. R. Tama, Tehnik Difraksi Sinar-X Dalam Analisis Struktur Kristal. .

K. Mader, W.;Kelm, “Synthesis and structural analysis of epsilon-(Fe2 O3),” Zeitschrift fuer Anorg. und Allg. Chemie, vol. 631, no. 0, pp. 2383–2389, 2005.

M. A. Gdaiem, S. Ghodhbane, A. Dhahri, J. Dhahri, and E. K. Hlil, “Effect of cobalt on structural, magnetic and magnetocaloric properties of La0.8Ba0.1Ca0.1Mn1-xCoxO3 (x = 0.00, 0.05 and 0.10) manganites,” J. Alloys Compd., vol. 3, 2016.

I. N. Rahman, “Pengaruh Substitusi Cu Terhadap Sifat Kemagnetan dan Kelistrikan Material La0.7(Ba0.97Ca0.03)0.3Mn1-xCuxO3 (x = 0; 0,03; 0,05; 0,07 dan 0,10),” Universitas Indonesia, 2019.




DOI: https://doi.org/10.15408/fiziya.v3i2.17638 Abstract - 0 PDF - 0

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