Preconcentration of Ion Ni(II) using Ca-Alginate Modified Resin with Dimethylglyoxime as a Filler Material of Column

Aman Sentosa Panggabean, Wirdhaningsih Wirdhaningsih, Subur P. Pasaribu

Abstract


The research about the preconcentration of Ni(II) ions using Ca-alginate resin modified with dimethylglyoxime (DMG) as a material filler of the column has been done. The stage of preconcentration done by using the water sample was passed through the column, then eluted using HNO3. The amount of Ni(II) in the eluate was measured using atomic absorption spectrophotometer (AAS). Several important parameters in the preconcentration stage have been studied. The optimal condition at the stage of preconcentration Ni(II) ions was retention at pH 4, the volume of sample was 10 mL, the volume of HNO3 eluent was 4 mL at a concentration of 1.5 M, with the retention of capacity value was 2.4657 mg Ni(II)/g resin. The analytical performance of this method is good, showed with repeatability value as a percentage of the coefficient of variance value was 4.06%, and can increase the limit detection of Ni(II) ions was 3.94 times if compared to direct measurements with AAS. The method can be applied to the determination of Ni(II) ions in the water samples from Mahakam river at port Samarinda with recovery percentage value was > 95 %, indicating that the matrix of samples did not affect the results of measurements.

Keywords


AAS; Ca-alginate-DMG; Ni(II); preconcentration

References


Amran MB, Panggabean AS, Sulaeman A, Rusnadi M. 2011. Preparation of a chelating resin and its application as a preconcentration system for determination of cadmium in river water by flow injection analysis. Int. J. Env Res. II:531–536.

Chen JP, Wang L. 2001. Characterization of a Ca-alginate based ion-exchange resin and its application in lead, copper, and zinc removal. Separation Science and Technology. 36(16): 3617-3637.

Darwin C, Panggabean AS, Alimuddin. 2016. Sintesis resin pengkhelat polystirena divinyl benzena-dimetilglioksima dan kemampuan adsorpsi terhadap ion logam Ni(II). J. Atomik. 2(1): 128-133.

Fuks L, Filipiuk D, Majdan M. 2006. Transition metal complexes with alginate biosorbent. J. of Mol. Struct. 792-793:104-109.

Garfield FM. 1991. Quality Assurance Principles for Analytical Laboratories. AOAC International, USA.

Karimi MA, Kafi M. 2015. Removal, preconcentration and determination of Ni(II) from different environmental samples using modified magnetite nanoparticles prior to flame atomic absorption spectrometry. Arabian Journal of Chemistry. 8: 812–820.

Kaur A, Gupta U. 2009. Preconcentration of Nickel using chemically modified silica nanoparticles. Eurasian J. Anal. Chem. 4(2): 175-183.

Koesmawati TA, Moelyo M, Rizqiani A, Tanuwidjaja S. 2017. Pre-concentration of Pb, Cd, and Ni in river water using back extraction method. In IOP Conf. Series: Earth and Environmental Science. 60(1): 012-021.

Miller JC, Miller JN. 1991. Statistika Untuk Kimia. Edisi Kedua. Bandung (ID): ITB Press.

Miro M, Frenzel W. 2014. Flow-through sorptive preconcentration with direct optosensing at solid surfaces for trace ion analysis. Trends in Analytical Chemistry. 23(1): 49-53.

Mørch A, Donati I, Strand LB, Skajak-Braek G. 2006. Effect of Ca2+, Ba2+, and Sr2+ on alginate microbeads. Biomacromolecules. 7: 1471-1480.

Naeemullah, Kazi TG, Shah F, Afridi HI, Khan S, Arian SS, Brahman KD. 2012. A green preconcentration method for determination of cobalt and lead in fresh surface and waste water samples prior to flame atomic absorption spectrometry. Journal of Analytical Methods in Chemistry. 20: 1-8.

Panggabean AS, Pasaribu SP, Bohari, Nurhasanah. 2014. Preconcentration of Chromium (VI) at trace levels using acid alumina resin with column method.Indones. J. Chem. Sci.14(1): 51–56.

Panggabean AS, Pasaribu SP, Sari IYL. 2012. Prakonsentrasi ion Cu(II) menggunakan resin berbasis mikrokapsul Ca-Alginat secara off-line dengan metode kolom. Chem. Prog. 5(2): 70–76.

Panggabean AS, Pasaribu SP, Amran MB. 2010. Chelating resin as preconcentration system for the determination of trace lead based on flow injection analysis method. Proc. Int. Conf. Math. Nat. Sci. Bandung.

Panggabean AS, Yusuf B. 2015. Determination of Chromium (VI) by using chitosan-1,5-diphenyl carbazide resin modified at the preconcentration system with colomn method. Int. J. Pharma and Bio Sci.6(3): 101–111.

Rapp I, Schlosser C, Rusiecka D, Gledhill M, Achterberg EP. 2017. Automated preconcentration of Fe, Zn, Cu, Ni, Cd, Pb, Co, and Mn in seawater with analysis using high-resolution sector field inductively-coupled plasma mass spectrometry. Anal. Chim. Acta. 976(11): 1-13.

Sari RJ, Panggabean AS,Erwin. 2016. Pemanfaatan resin Ca-alginat termodifikasi dengan etilen diamina tetraasetat (EDTA) dalam tahapan prakonsentrasi ion Mn(II) berbasis metode kolom. J. Atomik.1(1): 28–35.

Suwarsa S, Buchari, Panggabean AS. 2008. Pengembangan metode prakonsentrasi dengan teknik injeksi alir untuk analisis Cu2+ dan Pb2+ dalam air aliran sungai Citarum dan waduk Saguling. J. Mat. dan Sains. 13: 1–6.

Thubkhum N, Tangtreamjitmun. 2018. Determination of Nickel by flame atomic absorption spectrometry after preconcentration by coprecipitation with aluminum hydroxide. Anal. Sci. 34: 849-851.


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DOI: 10.15408/jkv.v6i1.7700

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